With 34 total appearances in Copa America, former Chile goalkeeper Sergio Livingstone holds the record for most appearances at the tournament. He achieved this record throughout six tournaments between 1941 and 1953. However, he never won the competition, with his best finish being third place on two occasions.
Livingstone made his debut for Chile at the South American Championship, now known as the Copa America, in 1941, in a 5-0 win. He was considered the best player in the tournament as he and Chile finished third.